Stable, High Voltage LiMn1.5Ni0.5O4 (LMNO) Cathode for Lithium-ion Batteries
The Problem
Cathode material selection has traditionally dominated the cost and energy-density limits of Lithium-ion batteries. Spinel oxide cathode chemistries such as LMNO demonstrate high-energy density and high operating voltage but have been hindered by rapid capacity decay during cycling because of the unstable structure of the manganese and nickel elements along with Jahn-Teller distortion effects.
The Solution
Researchers at the University of Tennessee have developed a new LMNO cathode and optimized synthesis method which minimizes capacity fade during cycling, enhances the stoichiometric ratio for LMNO production, and retains high phase purity. This technology’s chemical synthesis method features a toxic-free precursor for greater stability, nanoparticle surface modifications, and a network of carbon nanotubes to facilitate fast lithium-ion transport. Production of LMNO cathode in this manner will limit instability in cycling while realizing the advantages of high energy density and operating voltage of LMNO. Applications include EVs, e-VTOL aircraft, grid energy storage, and other high-Voltage Li-battery applications.
Benefits
| Benefit |
|---|
| Extended Performance - primary LMNO nanoparticles exhibit very small capacity dropoff after 1000 cycles (only 14 mAh g-1). |
| High Density - energy densities as high as 650 W-h/kg, at a discharge plateau voltage of 4.7 V. |
| Scalable – facile chemical synthesis method. |
| Environmentally Safe -Cobalt-free cathode and non-toxic precursor. |
| Planned improvement to primary nanoparticle and secondary microparticle sizes for faster Li+ ion transport and lower diffusion length. |
More Information
- Gregory Sechrist
- Technology Manager
- 865-974-1882 | gsechris@tennessee.edu
- UTRF Reference ID: 23147
- Patent Status: Patent Pending
Innovators
Manikandan Palanisamy
Research Assistant Professor, Department of Mechanical, Aerospace, and Biomedical Engineering (MABE), Tickle College of Engineering, UT Knoxville
Dr. Palanisamy received his Ph.D. from the CSIR -Central Electrochemical Research Institute in 2015 in India. He is a research assistant professor for the MABE Department at UT. His research interests include Lithium-ion batteries, Solid-State Chemistry, and Crystal Structure studies.
Dr. Palanisamy received his Ph.D. from the CSIR -Central Electrochemical Research Institute in 2015 in India. ...
Matthew Mench, Ph.D.
Dean, Tickle College of Engineering, Condra Chair, and Chancellor’s Professor
Dr. Mench is an internationally recognized authority in electrochemical power conversion and storage, his expertise encompasses polymer electrolyte fuel cells, flow battery systems, biological energy systems, multi-phase transport and visualization, computational simulations of electrochemical and power conversion and energy systems, and electrochemical methods of hazardous waste conversion.
Dr. Mench is an internationally recognized authority in electrochemical power conversion and storage, his expe...
Doug Aaron, Ph.D.
Assistant Department Head, Undergraduate Programs, Research Assistant Professor, Department of Mechanical and Aerospace Engineering
Dr. Aaron’s research specializes in redox flow battery diagnostics, high energy density batteries, low-temperature fuel cells and electrolyzers, and other large electrochemical energy storage technologies.
Dr. Aaron’s research specializes in redox flow battery diagnostics, high energy density batteries, low-tempera...
